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Potentiometric Studies of the Complexation Properties of Selected Lanthanide Ions with Schiff Base Ligand.


ABSTRACT: The synthesis, characterization, and equilibrium studies of complexes of selected lanthanide ions Eu(III), Gd(III), and Tb(III) with the ligand 1,3-bis(3-bromo-5-chlorosalicylideneamino)-2-propanol (H3L) are reported. It was found that in the solid state, the complexes with the formulas [Eu(H3L)2(NO3)3], [Gd(H3L)2(NO3)3], and [Tb(H3L)2(NO3)3] are formed. In solution, complexes with stoichiometries of Ln(III):H3L 1:1 and 1:2 were obtained. The ligand H3L was isolated in crystalline form, and its molecular structure and conformation were determined by single-crystal X-ray diffraction analysis. The compounds were further character

SUBMITTER: Baranska J 

PROVIDER: S-EPMC12609344 | biostudies-literature | 2025 Oct

REPOSITORIES: biostudies-literature