Controllable synthesis of perovskite solid solutions as novel energetic materials <i>via</i> thermodynamic equilibrium.

ABSTRACT: Perovskite solid solutions have aroused interest in energy applications, owing to the capability of fine-tuning and enhancing performance to surpass ternary perovskites. Their synthesis, however, is hard to control in solution due to the intricate self-assembly process wherein components crystallize in undetermined ratios. Herein, we present a facile approach to the controllable synthesis of perovskite solid solutions in aqueous solution and develop perovskite solid solutions as a novel class of energetic materials for the first time. Specifically, the composition control of perovskite solid solutions is achieved through thermodynamic equilibrium of reaction crystallization in water, exhibiting a linear relationship with the natural logarithm of reactant concentrations. Based on Goldschmid

SUBMITTER: Li M 

PROVIDER: S-EPMC12616919 | biostudies-literature | 2026 Jan

REPOSITORIES: biostudies-literature