Synergistic Mechanism of an Ionic Liquid-Based Composite Surfactant-Stabilized Microemulsion for Effective Separation of Oily Sludge.

ABSTRACT: The reduction and harmless treatment of oily sludge are challenging tasks. As green solvents, ionic liquids (ILs) have been used to treat oily sludge effectively; however, their high price limits the applications. In this paper, an imidazolium-based IL 1-hexadecyl-3-methylimidazole chloride salt ([C₁₆mim]-Cl) was synthesized and compounded with Tween20 to obtain a composite surfactant that could be used as an emulsifier to prepare a microemulsion for the treatment of oily sludge. The composite surfactant exhibited the greatest synergistic effect at a mass ratio of 4:6. Under optimal conditions, the oil removal rate reached 94.90%, and the residual oil rate was reduced to 1.67%. Moreover, the microemulsion exhibited a high removal rate for asphaltenes (81.01%). The treatment mech

SUBMITTER: Li X 

PROVIDER: S-EPMC12631387 | biostudies-literature | 2025 Nov

REPOSITORIES: biostudies-literature