Electronic structure blurring-mediated solid-state H₂O₂ electrosynthesis with high productivity.

ABSTRACT: The development of H₂O₂ economy is hampered by the instability of liquid-state bulk H₂O₂ solutions (2H₂O₂ → 2H₂O + O₂; ΔG° = -117 kJ mol^-1). Comparatively, dispersing H₂O₂ molecules in solid-state materials would offer good physical stability with less of handling, leak and exposure risks, but suffers from fabrication schemes irrelevant to commercial applications. Mediated by the concept of electronic structure blurring, here we elaborate one-step electrosynthesis of solid-state H₂O₂ with productivity up to 0.943 mol L^-1 h^-1. Notably, the as-fabricated solid-state H₂O₂ features not only high H₂O

SUBMITTER: Zhang Y 

PROVIDER: S-EPMC12645009 | biostudies-literature | 2025 Nov

REPOSITORIES: biostudies-literature