Ruthenium Bis-Sulfonate Complexes: Synthesis and Application in Asymmetric Hydrogenation.

ABSTRACT: A series of Ru-(L)-(X)₂ complexes (L = bidentate ligand; X = OMs, OTs, OTf) was synthesized and characterized. Ru-(BINAP)-(OMs)₂ showed improved catalytic performance over the established Ru-(BINAP)-(OAc)₂ catalyst, highlighting the impact of anion variation on catalytic asymmetric hydrogenations.

SUBMITTER: Zhou Y 

PROVIDER: S-EPMC12648767 | biostudies-literature | 2025 Nov

REPOSITORIES: biostudies-literature