1D Silver Organochalcogenide Semiconductors: Color Tunable Luminescence, Polarized Emission, and Long-Range Exciton Diffusion.

ABSTRACT: Metal organochalcogenides (MOCs) represent a promising class of organic-inorganic hybrid semiconductors with unique light-matter interactions. Their hybrid nature enables extensive structural and optoelectronic tunability via ligand engineering. In this study, we systematically modulated the electronic properties of ligands using Cl and Me functional groups, achieving precise control over the optoelectronic properties of Ag-based MOCs. Structural analysis revealed that these MOCs adopt a one-dimensional (1D) chain structure with organic ligands surrounding a Ag-chalcogen core. Density functional theory (DFT) calculations demonstrated that MOCs exhibit characteristics of 1D semiconductors with strongly dispersive conduction and valence bands aligned along the crystal rod directions. Experim

SUBMITTER: Sakurada T 

PROVIDER: S-EPMC12670413 | biostudies-literature | 2025 Oct

REPOSITORIES: biostudies-literature