Factors Impacting the Nuclear Magnetic Resonance Spectra of Electrolyte Adsorbed in Layered Metal-Organic Frameworks.

ABSTRACT: Electrically conductive layered metal-organic frameworks (MOFs) have a wide range of electrochemical applications including in sensors, batteries, spintronics, magnetic semiconductors, and supercapacitors. In these devices, MOF structure strongly influences performance, often through MOF-electrolyte interactions. However, few studies have directly probed these interactions at the electrochemical interface. Recent work showed that ¹⁹F NMR spectroscopy can probe organic electrolyte environments in the layered MOF Ni₃(HITP)₂ (HITP = 2,3,6,7,10,11-hexaiminotriphenylene), revealing that the chemical shifts of in-pore anions are influenced by specific chemical interactions with the MOF functionality. Here, we expand this approach to study ion adsorption in a rang

SUBMITTER: Balhatchet CJ 

PROVIDER: S-EPMC12670500 | biostudies-literature | 2025 Nov

REPOSITORIES: biostudies-literature