Ligand Electronic Properties Dictate Composition of Ni-Based Nanocrystals.

ABSTRACT: Colloidal nanocrystals (NCs) composed of transition metals are appealing for several applications, particularly for those related to their catalytic and magnetic properties. Yet, the chemical principles governing their synthesis remain underexplored compared to other classes of materials. In this study, we take inspiration from molecular inorganic chemistry and implement a systematic ligand screening strategy to elucidate ligand-induced effects in the synthesis of Ni-based NCs. Specifically, we investigate the impact of organo-pnictide ligands with varying steric and electronic properties (i.e., PR₃, AsR₃, SbR₃) in the synthesis of nickel, nickel phosphide, nickel arsenide and nickel antimonide NCs. Using a multimodal characterization approach, we reveal th

SUBMITTER: Zaza L 

PROVIDER: S-EPMC12673580 | biostudies-literature | 2025 Nov

REPOSITORIES: biostudies-literature