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An organic array of quantum corrals modulated by the gold herringbone electronic superlattice.


ABSTRACT: The periodic herringbone reconstruction on the surface of Au(111) consists of alternating face-centered-cubic (fcc) and hexagonal-closed-packed (hcp) sites separated by dislocation lines and elbows. This well-known arrangement acts as an electronic superlattice for surface-state electrons, creating a mini-gapped band structure with a modulated electronic density. This rich and fascinating geometrical and electronic landscape has countless times served as a platform for molecular self-assembly and on-surface synthesis of carbon-based nanoarchitectures as well as a template for 2D material growth. In this work, we fabricated a long-range ordered organic quantum corral (QC) array via the self-assembly of 1,3,5-benzenetribenzoic acid molecules onto the herringbone reconstructed Au(111)

SUBMITTER: Li J 

PROVIDER: S-EPMC12678045 | biostudies-literature | 2025 Apr

REPOSITORIES: biostudies-literature