High-entropy perovskite oxides: Morphotropic phase boundary interfacial engineering for next-generation communications.

ABSTRACT: Precise atomic-level control over interfacial charge density and lattice distortions remains a critical challenge across electromagnetism, optoelectronics, and catalysis. Here, we introduce a high-entropy strategy that leverages local compositional disorder to synergistically manipulate charge density distribution and lattice strain at anisotropic morphotropic phase boundary (MPB) interfaces. Experimental and computational studies reveal that high-entropy effect stabilizes multiphase polar nanoclusters within high-entropy perovskite oxides (HEPOs). This unique structural feature drives efficient charge density redistribution, substantially enhancing MPB interfacial polarization. We showcase this approach in electromagnetism, where MPB interfacial engineering effectively transforms perovski

SUBMITTER: Yao K 

PROVIDER: S-EPMC12680061 | biostudies-literature | 2025 Dec

REPOSITORIES: biostudies-literature