ABSTRACT: Paper plays an important role in the packaging industry due to its low cost, light weight, recyclability and biodegradability. However, the use of paper as a packaging material is severely limited due to its hydrophilicity caused by the hydroxyl groups of cellulose. This study reports a simple preparation of highly hydrophobic kraft paper by a one-step dip coating method using [3-(2,2,3,3-tetrafluoropropoxy)propyl]silsesquioxane, {3-[(2,2,3,3,4,4,5,5-octafluoropentyl)oxy]propyl}silsesquioxane or {3-[(2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl)oxy]propyl}silsesquioxane as hydrophobic agents. As a result of modification of kraft paper, a stable covalently bonded coating is formed on its surface. The coated kraft paper has demonstrated (1) high water resistance (the water contact angle (WCA)