Real-Time In Situ Imaging of Aggregation-Induced Emission and Solvent-Guided Morphogenesis of a "V-Shaped" 4-Amino-1,8-Naphthalimide Troger's Base Supramolecular Scaffold.

ABSTRACT: The influence of solvent polarity on the self-assembly processes and its effect on the morphological outcome of self-assembled aggregates is another domain that requires a comprehensive study. The present investigation aims to address these issues by employing a unique "V-shaped" luminogen (TBNap, N-(3-pyridyl)-4-amino-1,8-naphthalimide Tröger's base), where the two 1,8-naphthalimide units are nearly orthogonal to each other. The TBNap is synthesized in high yield and fully characterized using standard characterization methods, including X-ray diffraction analysis, which reveals distinctly different structural arrangements of TBNap crystallized as different solvates in various solvent media. Furthermore, due to its internal charge transfer nature, the TBNap exhi

SUBMITTER: Shanmugaraju S 

PROVIDER: S-EPMC12697783 | biostudies-literature | 2025 Dec

REPOSITORIES: biostudies-literature