Switchable proton conduction driven by UV/NIR-induced electron transfer in an inorganic-organic hybrid gallium phosphate-oxalate open-framework.

ABSTRACT: Conventional proton-conducting materials often fail to meet the responsiveness and flexibility required for emerging technologies such as the Internet of Things (IoT) and robotics, driving significant interest toward the development of dynamically switchable and tunable proton conductors. Herein, we present a novel UV/NIR-responsive gallium phosphate-oxalate inorganic-organic hybrid, {(H₃TPT)[Ga₂(H₂PO₄)₂(C₂O₄)₃]·H₂PO₄·H₃PO₄} _n (NEU25, TPT = 2,4,6-tris(4-pyridyl)-1,3,5-triazine; C₁₈N₆H₁₂) synthesized via an ionothermal decomposition-reconstruction strategy within a deep eutectic solvent (DES) system. Ben

SUBMITTER: Huang S 

PROVIDER: S-EPMC12712630 | biostudies-literature | 2026 Feb

REPOSITORIES: biostudies-literature