Electroluminescence From a 1D Metal-Organic Chalcogenide Enabled by a Minute-Scale Facile Synthesis.

ABSTRACT: Metal-organic chalcogenides (MOCs) represent a unique materials platform promising to overcome the respective stability and structural integrity challenges of perovskites and functionalized dichalcogenides. However, their practical application is hindered by slow, multi-day synthesis methods that produce low-quality films. Here, these challenges are addressed with a vapor-assisted solution process that enables the ambient-pressure fabrication of 1D MOC, silver(I) 2-methyl ester benzenethiolate (AgSPhCOOMe), films within 5 min. The resulting dense, pinhole-free AgSPhCOOMe films exhibit a high photoluminescence quantum yield of 37.5%, with bright, broadband emission originating from self-trapped excitons due to the material's strong electron-phonon coupling. This scalable synthesis platform

SUBMITTER: Chin SH 

PROVIDER: S-EPMC12713059 | biostudies-literature | 2025 Dec

REPOSITORIES: biostudies-literature