Structural Diversity and Tunable Emission in Hybrid Organic-Inorganic Copper(I) Bromides.

ABSTRACT: Recently, hybrid organic-inorganic copper(I) metal halides have attracted global attention due to their intriguing optical properties and low-cost solution processability. In this work, we report three hybrid organic-inorganic copper(I) bromides, [TMPA]₂[Cu₂Br₄], [TMPA]₄[Cu₆Br₁₀], and [TMPA]₂[Cu₄Br₆], synthesized through a slow evaporation method using trimethylphenylammonium (TMPA⁺) as the organic cation. By precise control of the CuBr and TMPABr precursors, different copper halide [Cu₂Br₄]^2-, [Cu₆Br₁₀]^4-, and [Cu₄Br₆]^2- structural units can be obtained. [TMPA]₂[Cu_2</

SUBMITTER: Pinky T 

PROVIDER: S-EPMC12728924 | biostudies-literature | 2025 Dec

REPOSITORIES: biostudies-literature