Thermal responsive Rh₁-Pd single-atom catalyst for controlling activity in direct formic acid fuel cells.

ABSTRACT: Single-atom catalysts are highly active for specific reactions; however, their sinter-resistance and clean surfaces make it difficult to impart them with a "smart" property. Herein we design a thermosensitive single-atom Rh₁-Pd nanosheets (NSs) by employing amino functionalized poly(N-isopropylacrylamide) as thermal responsive gate for the "open"/"closed" control of electro-catalytic activity. Using formic acid electro-oxidation as model reaction, the thermosensitive Rh₁-Pd NSs exhibit high mass activity (2.29 A mg_PGM^-1), strong poisoning resistance, and reversible thermo-responsibility at a lower critical solution temperature (LCST) of 35 ^oC. In-situ spectroscopy and theoretical investigations reveal that the d-electron deficient Rh

SUBMITTER: Su K 

PROVIDER: S-EPMC12748949 | biostudies-literature | 2025 Dec

REPOSITORIES: biostudies-literature