Temperature-regulated synthesis of carbonate-pillared zinc-triazolate frameworks for precise molecular recognition.

ABSTRACT: The efficient discrimination of industrially relevant gases, particularly those with closely analogous physicochemical properties, remains a formidable challenge within the realm of adsorptive separation technologies. Achieving satisfactory separation efficiency poses stringent requirements on the precise control over the pore structures of adsorbents. Here we introduce a strategy for the precise modulation of pore structures in a carbonate-pillared Zn-triazolate framework, Zn₂(datrz)₂CO₃ (datrz = 3,5-diamino-1,2,4-triazolate), through the straightforward adjustment of the solvothermal synthesis temperature. Utilizing this approach, we have successfully fabricated a series of Zn₂(datrz)₂CO₃ materials with tunable pore struct

SUBMITTER: Liu J 

PROVIDER: S-EPMC12749236 | biostudies-literature | 2025 Dec

REPOSITORIES: biostudies-literature