Dataset Information
Steric Pruning Unlocks Hierarchical Structuring, Thermochromism, C-H/O Activation, and 6-electron Redox Transmetalation in Planar Bismuth Triamides.
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ABSTRACT:
SUBMITTER: Howlett WP
PROVIDER: S-EPMC12759222 | biostudies-literature | 2026 Jan
REPOSITORIES: biostudies-literature
Publications
Steric Pruning Unlocks Hierarchical Structuring, Thermochromism, C-H/O Activation, and 6-electron Redox Transmetalation in Planar Bismuth Triamides.
Angewandte Chemie (International ed. in English) 20251117 1
Planar bismuth triamides with tunable stereoelectronics offer a versatile platform for studying the effects of geometric constraints in p-block elements. Here we show that exploring the low steric bulk regime in these compounds unlocks categorically new phenomena such as epitaxial hierarchical ordering, thermochromism, C─H/O activation, and 6-electron pincer-to-pincer redox transmetalation. These behaviors are not observed in sterically encumbered derivatives, emphasizing the role of steric modu ...[more]