Toward the Development of a Uranium-Based Redox-Flow Battery.

ABSTRACT: An all-uranium-based electrochemical cell consisting of simple [U^IV/V(^tBuacac)₄]^0/+ and [U^III/IV(N(SiMe₃)₂)₄]^-/0 complexes as anolyte and catholyte species was constructed with a cell voltage of 2.2 V. The [U^IV(^tBuacac)₄] (1) and [U^IV(N(SiMe₃)₂)₄] (2) complexes have favorable properties for redox-flow-battery applications, including reversible redox chemistry, relatively high stability toward electrochemical cycling, and high solubility in common organic solvents. The [U^III/IV(N(SiMe₃)₂)₄]^-/0 complexes were first isolated and characterized by Schelter et al., and

SUBMITTER: Waldschmidt P 

PROVIDER: S-EPMC12767275 | biostudies-literature | 2026 Jan

REPOSITORIES: biostudies-literature