Nanoscale chemical imaging of pseudocapacitive charge storage in MXenes.

ABSTRACT: Pseudocapacitive materials store electrochemical energy through fast and reversible surface charge transfer reactions. Titanium carbide MXenes are two-dimensional materials which have shown redox or intercalation pseudocapacitive properties depending on the electrolyte. Nevertheless, the intrinsic pseudocapacitive charging mechanism in individual MXene flakes remains unresolved. Here, we employ in situ scanning transmission X-ray microscopy (STXM) to map the local chemical changes in individual Ti₃C₂T_x MXene flakes during spontaneous and electrochemical intercalation of protons and lithium ions in aqueous electrolytes. Our investigations reveal that proton and lithium-ion intercalation induces a reduction and an oxidation, respectively, of the titani

SUBMITTER: Sharma N 

PROVIDER: S-EPMC12767768 | biostudies-literature | 2026 Jan

REPOSITORIES: biostudies-literature