Efficient singlet fission in rubicene null aggregates.

ABSTRACT: The singlet fission (SF) photovoltaic applications are currently restricted by the limited number of practical SF materials and the lack of understanding of the underlying SF mechanism in typical molecular aggregates. Null-aggregates are molecular aggregates that exhibit minimal exciton-exciton interactions, leading to a monomer-like spectroscopic signature, and thus hold distinct advantages in bypassing extra energy loss and excimer trap issues in conventional H- and J-aggregates. However, it remains unknown if null-aggregates could also contribute to an efficient SF process. In this work, we present an efficient SF system based on rubicene null aggregates. The comprehensive structural and spectroscopic studies demonstrate that the destructive interference between long-range Coulomb and s

SUBMITTER: Shi X 

PROVIDER: S-EPMC12776612 | biostudies-literature | 2026 Feb

REPOSITORIES: biostudies-literature