Diffusion of Nanorods with Various Lengths and Rigidities in Cross-Linked Networks.

ABSTRACT: We investigated diffusion of thin and thick nanorods with varying lengths and rigidities in cross-linked polymer networks using coarse-grained molecular dynamics (CGMD) simulations. Our results show that the translational diffusion of nanorods slows down with power scaling laws as their length increases, exhibiting a non-monotonic dependence on rigidity of thin nanorods, and decreases with the rigidity of thick nanorods. The sub-diffusion of nanorods is observed at short time scales, which becomes more pronounced for rigid nanorods. The nanorods show anisotropic diffusion behavior with favoring motion along their major axes in cross-linked networks, and the anisotropy enhances by increasing either rigidity or length of nanorods, especially for thick nanorods. The sub-diffusion behavior of

SUBMITTER: Li B 

PROVIDER: S-EPMC12787724 | biostudies-literature | 2025 Dec

REPOSITORIES: biostudies-literature