Thermal conductivity modeling beyond the dilute limit using a body-centered cubic framework for densely packed polymer composites.

ABSTRACT: Existing models of thermal conductivity in polymer composites typically address dilute to semi-dilute filler concentrations (≤ 40 vol%) yet fail to capture the strong interactions that arise when fillers are closely packed. In densely filled systems, these interactions reorganize heat transport according to the principles of thermal resistance, directing it along preferred pathways. In this study, we introduce a mechanistic thermal conductivity model based on a simplified body-centered cubic framework. This model effectively captures the essential impact of reduced interparticle distances and enhanced filler interactions in densely packed composites, enabling a more accurate description of heat flow by forcing it to follow the least-resistance pathways. This approach delivers high-precisio

SUBMITTER: He L 

PROVIDER: S-EPMC12789673 | biostudies-literature | 2025 Dec

REPOSITORIES: biostudies-literature