Flash-Infrared-Annealing-Enabled High-Temperature Sintering of Photoanodes on Flexible Polymer Foils for Ultralight Photovoltaics.
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ABSTRACT: Ultralight photovoltaics are indispensable wherever every gram counts, from self-powered Internet of Things nodes to free-hanging greenhouse covers. In dye-sensitized solar cells (DSCs) the required 450-500 °C sintering of the mesoporous TiO2 (m-TiO2) photoanode has so far limited the use of polymer substrates. Here, we replace the furnace step with flash infrared annealing. Near-IR radiation heats the 3.5 μm m-TiO2 layer to 550 ± 20 °C while keeping a 12.5 μm indium-tin-oxide/polyimide foil below 170 °C with a water-cooled heat-sink. We obtain complete removal of organic binders, while the substrate sheet resistance increases modestly from 60.2 to 129.8 Ω sq-1. Flexible DSCs reach power conversion efficiencies of 5.10% under AM 1.5G illumination
SUBMITTER: Bradford D
PROVIDER: S-EPMC12797324 | biostudies-literature | 2026 Jan
REPOSITORIES: biostudies-literature
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