Synthesis, crystal structure and Hirshfeld surface analysis of a coordination compound of silver nitrate with 2-amino-benzoxazole.
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ABSTRACT: The coordination complex of 2-amino-benzaxole (2AB) with silver(I), namely, bis(2-aminobenzoxazole-κN)silver(I) nitrate-bis(2-aminobenzoxazole (1/2), [Ag(C7H6N2O)2]NO3·2C7H6N2O or [Ag(2AB)2]NO3·(2AB)2, was synthesized from ethanol solutions of AgNO3 and 2AB. The asymmetric unit contains one mol-ecule of [Ag(2AB)2]NO3·(2AB)2, The central silver(I) atom is coordinated by two nitro-gen donor atoms from 2-amino-benzaxazole ligands in an N2 coordination set while another two 2-amino-benzaxazole ligands and one nitrate anion remain uncoordinated. The crystal structure features several intra-molecular N-H⋯O and N-H⋯N
SUBMITTER: Razzoqova S
PROVIDER: S-EPMC12810307 | biostudies-literature | 2025 Dec
REPOSITORIES: biostudies-literature
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