Solvation Entropy as a Lever for Steering the Macroscopic Properties of a Functional Supramolecular Helical Polymer.

ABSTRACT: Solvent-solute interactions are utterly important in supramolecular polymers (SPs), yet the high responsivity of SPs to solvent polarity makes it challenging to play on other solvation effects to tune their macroscopic properties in a rational manner. Herein, we report the characterization at various scales of the assembly properties of a C₂-symmetric benzene-1,3,5-tricarboxamide monomer with two (1S)-methylheptyl moieties and one diphenylphosphino group as lateral chains. Our investigation reveals a highly cooperative structural transition between two SP states, which can exquisitely be tuned by solvents of similar polarities, leading to variation of the transition temperature (T*) over a range of 85 K. The structural transition was detected in 4 pure solvents and 13 toluene/co

SUBMITTER: Kong H 

PROVIDER: S-EPMC12811656 | biostudies-literature | 2026 Jan

REPOSITORIES: biostudies-literature