Coordination Polymers Driven by Urea-Diisophthalate Linkers: From Hydrothermal Assembly and Structural Diversity to Catalytic Applications.

ABSTRACT: Eight new metal(II) coordination polymers (CPs) were assembled via hydrothermal methods from an unexplored urea-diisophthalate linker, 5,5'-(carbonylbis(azanediyl))diisophthalic acid (H₄cada) and different N-donor auxiliary ligands (phen: 1,10-phenanthroline; bipy: 2,2'-bipyridine; H₂biim: 2,2'-biimidazole; bpa: bis(4-pyridyl)amine; dpey: 1,2-di(4-pyridyl)ethylene; or dpea: 1,2-di(4-pyridyl)ethane). The obtained products were identified as [Mn(μ₃-H₂cada)(phen)(H₂O)]_n·2nH₂O (1), [Mn₂(μ₄-cada)(phen)₃(H₂O)]_n·2nH₂O (2), [M₂(μ₅-cada)(bipy)₂(H₂O)₂]_n

SUBMITTER: Chen Y 

PROVIDER: S-EPMC12818755 | biostudies-literature | 2025 Sep

REPOSITORIES: biostudies-literature