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Fallen-leaf-sensitized biosolar oxygenation of hydrocarbons.


ABSTRACT: Lignocellulosic wastes are naturally abundant carbon resources but have been underutilized due to their complex structure and recalcitrant nature. They require energy- and water-intensive processes, such as thermal, chemical, and/or mechanical pretreatments, for their valorization. Here, we report a new function of raw tree waste for driving the solar-powered oxygen reduction reaction (ORR) and biocatalytic oxyfunctionalization of hydrocarbons. We reveal that various lignocellulosic wastes, such as fallen leaves, waste wood, and wastepaper, can produce hydrogen peroxide (H2O2) using only O2, water, and light without any pretreatment. In particular, fallen leaves from Platanus trees exhibit high rates of ORR, which is ascribed to their superior photop

SUBMITTER: Lee M 

PROVIDER: S-EPMC12820941 | biostudies-literature | 2026 Jan

REPOSITORIES: biostudies-literature