Mossbauer Spectroscopy on Antimony Borosulfates Reveals Weak Coordination Behavior.

ABSTRACT: With M^IIIM^I[B(SO₄)₂]₄ (M^III = Bi³⁺, Sb³⁺, Lu³⁺; M^I = H₃O⁺, NO₂ ⁺, Li⁺, Na⁺, K⁺, Rb⁺, Cs⁺), we recently described the first modular system within borosulfate chemistry comprising a three-dimensional anion. Herein, we shed light on the respective series of antimony compounds SbX[B(SO₄)₂]₄ (X = Li⁺, Na⁺, K⁺, Rb⁺, Cs⁺, Ag⁺, Tl⁺, NO⁺, NH₄ ⁺). While maintaining the same anionic topology, the compounds crystallize in the space groups I 4¯$\bar{4}$ (no

SUBMITTER: Turgunbajew E 

PROVIDER: S-EPMC12828460 | biostudies-literature | 2026 Jan

REPOSITORIES: biostudies-literature