Time of flight secondary ion mass spectrometry imaging of contaminant species in chemical vapour deposited graphene on copper.

ABSTRACT: Time of flight secondary ion mass spectrometry (ToF-SIMS) was used to probe the chemistry of graphene grown on copper foil substrates by chemical vapour deposition (CVD) under various growth conditions. The surface sensitivity, mass resolving power, and imaging capability of ToF-SIMS allow us to explore variations in the chemical species present on the graphene surface, as well as in three dimensions under the graphene. In this way, we can observe the impact that variations in the chemical composition of the copper foil have on the growth of the graphene; in particular, the accumulation of contaminations present in the copper foil, which has implications for the potential electrical properties of the graphene. We also observe variations in the permeation of oxygen underneath the graphene l

SUBMITTER: Brennan B 

PROVIDER: S-EPMC12834054 | biostudies-literature | 2026

REPOSITORIES: biostudies-literature