Halogen as Template to Modulate the Structures of the Nanocage-Based Silver(I)-Thiolate Coordination Polymers.

ABSTRACT: By the reaction of AgNO₃, 2-methyl-2-propanethiol (HStBu), with various-sized halogen ions as templates, three multi-nuclear silver-thiolate cluster-based chain-like coordination polymers, [Ag₆(μ-SBu)₆]_n (USC-CP-2), [Ag₆(μ-StBu)₅Br]_n (USC-CP-4) and [Ag₁₄(μ-StBu)₁₂I₂]_n (USC-CP-3) constructed by different Ag(I)-nanocages, have been synthesized and characterized by X-ray diffraction analyses. With F^-, Cl^- or without template, USC-CP-2 exhibits a one-dimensional structure composed of detached Ag₆-cages, absent of fluoride or chloridion. While with Br^- and I^-

SUBMITTER: Tan C 

PROVIDER: S-EPMC12844137 | biostudies-literature | 2026 Jan

REPOSITORIES: biostudies-literature