Heavy Prussian Blue Analog with Magnetic Ordering above 400 K.

ABSTRACT: Molecule-based magnets hold promise for a variety of applications in information technologies owing to their chemical tunability. This feature can facilitate the integration of desired magnetic properties alongside additional functionalities within a single material. Although numerous cyanido-bridged assemblies are identified as multifunctional materials at cryogenic temperatures, achieving analogous behavior at room temperature remains a challenge. This study reports a cyanido-bridged compound, which shows ferrimagnetic ordering with a critical temperature exceeding 400 K. This breakthrough is achieved through the mechanochemical synthesis of vanadium(II)-hexacyanomolybdate(III) Prussian Blue Analog (PBA) under anhydrous conditions. The ferrimagnetic order is evidenced by SQUID (SQUID = s

SUBMITTER: Magott M 

PROVIDER: S-EPMC12850227 | biostudies-literature | 2026 Jan

REPOSITORIES: biostudies-literature