Tailored Plasticization of Bio- and Fossil-Based Polymers Using a Versatile Bioplasticizer Derived from Phenylacetic Acid and Glycerol.
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ABSTRACT: For accelerating the shift from fossil-derived plastics toward biopolymers, there is an urgent need to develop efficient and versatile biobased plasticizers to improve biopolymer performance without compromising biodegradability and/or safety. This study explores the versatility of the emerging triphenylacetic glyceroate (TPAG) bioplasticizer by incorporating it into a range of biobased and conventional polymers. An increasing content of TPAG, from 5 to 20 parts per hundred of resin (phr), has been compounded with polyhydroxybutyrate (PHB), polyhydroxybutyrate-co-valerate (PHBV), polyvinyl chloride (PVC), and polybutylene succinate (PBS), which present complicated processability and/or limited mechanical properties as bare polymers. Differential scanning calorimetry reveals a clear
SUBMITTER: Martellosio L
PROVIDER: S-EPMC12903500 | biostudies-literature | 2026 Feb
REPOSITORIES: biostudies-literature
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