A new multifunctional one-dimensional bromo-bismuthate(iii): synthesis, structural features, characterization, and optical properties of (C₁₀H₁₃N₄)[BiBr₄]·2H₂O.

ABSTRACT: A new one-dimensional bromobismuthate(iii) organic-inorganic hybrid (C₁₀H₁₃N₄)[BiBr₄]·2H₂O, was successfully synthesized and comprehensively investigated to elucidate its structural, thermal, and optoelectronic characteristics. Single-crystal X-ray diffraction established a monoclinic system (P2₁/n) with one-dimensional [BiBr₄] _n ^n- chains composed of edge-sharing BiBr₆ octahedra, stabilized through an extended network of hydrogen bonding and π-π stacking interactions. Vibrational spectroscopy (FTIR and Raman) confirmed the coexistence and coupling of organic-inorganic subunits, while thermogravimetric analysis demonstrated excellent stability up to 275

SUBMITTER: Alibi A 

PROVIDER: S-EPMC12908441 | biostudies-literature | 2026 Feb

REPOSITORIES: biostudies-literature