Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation.

ABSTRACT: An organosilicon cation stabilized by intramolecular pyridyl coordination was effectively generated and accumulated by oxidative Si-Si bond dissociation of the corresponding disilane using low temperature electrolysis, and was characterized by NMR and CSI-MS.

SUBMITTER: Nokami T 

PROVIDER: S-EPMC1810300 | biostudies-literature | 2007 Feb

REPOSITORIES: biostudies-literature