High-yield hydrogen production from starch and water by a synthetic enzymatic pathway.

ABSTRACT:

Background

The future hydrogen economy offers a compelling energy vision, but there are four main obstacles: hydrogen production, storage, and distribution, as well as fuel cells. Hydrogen production from inexpensive abundant renewable biomass can produce cheaper hydrogen, decrease reliance on fossil fuels, and achieve zero net greenhouse gas emissions, but current chemical and biological means suffer from low hydrogen yields and/or severe reaction conditions.

Methodology/principal findings

Here we demonstrate a synthetic enzymatic pathway consisting of 13 enzymes for producing hydrogen from starch and water. The stoichiometric reaction is C(6)H(10)O(5) (l)+7 H(2)O (l)-->12 H(2) (g)+6 CO(2) (g). The overall process is spontaneous and unidirectional because of a negative Gibb

SUBMITTER: Zhang YH 

PROVIDER: S-EPMC1866174 | biostudies-literature | 2007 May

REPOSITORIES: biostudies-literature