Cluster reactivity experiments: employing mass spectrometry to investigate the molecular level details of catalytic oxidation reactions.

ABSTRACT: Mass spectrometry is the most widely used tool in the study of the properties and reactivity of clusters in the gas phase. In this article, we demonstrate its use in investigating the molecular-level details of oxidation reactions occurring on the surfaces of heterogeneous catalysts via cluster reactivity experiments. Guided ion beam mass spectrometry (GIB-MS) employing a quadrupole-octopole-quadrupole (Q-O-Q) configuration enables mass-selected cluster ions to be reacted with various chemicals, providing insight into the effect of size, stoichiometry, and ionic charge state on the reactivity of catalyst materials. For positively charged tungsten oxide clusters, it is shown that species having the same stoichiometry as the bulk, WO(3)(+), W(2)O(6)(+), and W(3)O(9)(+), exhibit enhanced acti

SUBMITTER: Johnson GE 

PROVIDER: S-EPMC2587532 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature