Optimal TBHP allylic oxidation of Delta5-steroids catalyzed by dirhodium caprolactamate.

ABSTRACT: Dirhodium caprolactamate is the most efficient catalyst for the oxidation of Delta5-steroids to 7-keto-Delta5-steroids by 70% tert-butyl hydroperoxide in water (T-HYDRO). Isolated product yields range from 38 to 87%.

SUBMITTER: Choi H 

PROVIDER: S-EPMC2596589 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature