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Dinuclear Zn-catalyzed asymmetric alkynylation of unsaturated aldehydes.


ABSTRACT: Our recent development of a proline-derived bimetallic catalyst has led to a number of efficient, catalytic, enantioselective transformations. Herein, we report a practical and general alkynylation of aromatic and alpha,beta-unsaturated aldehydes using our zinc catalyst system.

SUBMITTER: Trost BM 

PROVIDER: S-EPMC2596613 | biostudies-literature | 2006 Jan

REPOSITORIES: biostudies-literature