A promising change in the selection of the circular polarization excitation used in the measurement of Eu(III) circularly polarized luminescence.

ABSTRACT: A judicious change in the selected transition used for circular polarization excitation will overcome the low oscillator strength limitation of the currently allowed magnetic-dipole (5)D1 <-- (7)F2 (Eu(III)) transition chosen for circularly polarized luminescence (CPL) measurement. The proposed allowed magnetic-dipole (5)D1 <-- (7)F0 (Eu(III)) transition will facilitate the detection of CPL from the Eu(III) systems of interest. CPL on the acetonitrile solution of the chiral tris complex of Eu(III) with (R,R)-N,N'-bis(1-phenylethyl)-2,6-pyridinedicarboxamide ([Eu((R,R)-1)3](3+)), recently suggested as an effective and reliable CPL calibrating agent, confirms the feasibility of the proposed experimental procedure. A comparable CPL activity exhibited by the acetonitrile solution of [Eu((R,R)-

SUBMITTER: Do K 

PROVIDER: S-EPMC2628574 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature