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Direct and stereoselective synthesis of alpha-linked 2-deoxyglycosides.


ABSTRACT: alpha-Linked 2-deoxyglycosides were conveniently obtained by employing a glycosyl donor having a participating ( S)-(phenylthiomethyl)benzyl moiety at C-6, whereas 2,6-dideoxy-alpha-glycosides could be prepared by BF 3.Et 2O-promoted activation of allyl glycosyl donors.

SUBMITTER: Park J 

PROVIDER: S-EPMC2631667 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature