Synthesis and structure revision of nakiterpiosin.

ABSTRACT: This manuscript describes a convergent synthesis and the revision of the relative stereochemistry of nakiterpiosin, a marine C-nor-D-homosteroid. Our synthesis features a late-stage carbonylative Stille cross-coupling reaction and a photo-Nazarov cyclization reaction that deliver the complete nakiterpiosin skeleton efficiently.

SUBMITTER: Gao S 

PROVIDER: S-EPMC2635422 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature