Synthesis of amidines using N-allyl ynamides. A palladium-catalyzed allyl transfer through an ynamido-pi-allyl complex.

ABSTRACT: A de novo transformation of N-allyl-N-sulfonyl ynamides to amidines is described featuring a palladium-catalyzed N-to-C allyl transfer via ynamido-palladium-pi-allyl complexes.

SUBMITTER: Zhang Y 

PROVIDER: S-EPMC2683379 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature