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Correlated Optical Spectroscopy and Transmission Electron Microscopy of Individual Hollow Nanoparticles and their Dimers.


ABSTRACT: The optical spectra of individual Ag-Au alloy hollow particles were correlated with the particles' structures obtained by transmission electron microscopy (TEM). The TEM provided direct experimental access to the dimension of the cavity, thickness of the metal shell, and the interparticle distance of hollow particle dimers with high spatial resolution. The analysis of correlated spectral and structural information enabled the quantification of the influence of the core-shell structure on the resonance energy, plasmon lifetime, and plasmon coupling efficiency. Electron beam exposure during TEM inspection was observed to affect plasmon wavelength and lifetime, making optical inspection prior to structural characterization mandatory.

SUBMITTER: Yang L 

PROVIDER: S-EPMC2685363 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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Correlated Optical Spectroscopy and Transmission Electron Microscopy of Individual Hollow Nanoparticles and their Dimers.

Yang Linglu L   Yan Bo B   Reinhard Björn M BM  

The journal of physical chemistry. C, Nanomaterials and interfaces 20080901 41


The optical spectra of individual Ag-Au alloy hollow particles were correlated with the particles' structures obtained by transmission electron microscopy (TEM). The TEM provided direct experimental access to the dimension of the cavity, thickness of the metal shell, and the interparticle distance of hollow particle dimers with high spatial resolution. The analysis of correlated spectral and structural information enabled the quantification of the influence of the core-shell structure on the res  ...[more]

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