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Stereoselective synthesis of the C(1)-C(19) fragment of tetrafibricin.


ABSTRACT: [reaction: see text] A stereoselective synthesis of the C(1)-C(19) fragment of tetrafibricin has been accomplished via a highly diastereoselective double allylboration reaction of 6-8 and an iodonium ion promoted urethane cyclization for the installation of the C(15) alkoxy function in 3.

SUBMITTER: Lira R 

PROVIDER: S-EPMC2701644 | biostudies-literature | 2007 Feb

REPOSITORIES: biostudies-literature