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Synthesis, characterization, and theory of [9]-, [12]-, and [18]cycloparaphenylene: carbon nanohoop structures.

ABSTRACT: The first synthesis and characterization of [9]-, [12]-, and [18]cycloparaphenylene was demonstrated utilizing a novel aromatization reaction. We refer to these fascinating structures as "carbon nanohoops" due to their structural similarity to carbon nanotubes. Additionally, we have utilized computational methods to understand the unique properties of these fully conjugated macrocycles.

SUBMITTER: Jasti R

PROVIDER: S-EPMC2709987 | biostudies-literature | 2008 Dec

REPOSITORIES: biostudies-literature

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Synthesis, characterization, and theory of [9]-, [12]-, and [18]cycloparaphenylene: carbon nanohoop structures.

Jasti Ramesh R Bhattacharjee Joydeep J Neaton Jeffrey B JB Bertozzi Carolyn R CR

Journal of the American Chemical Society 20081201 52

The first synthesis and characterization of [9]-, [12]-, and [18]cycloparaphenylene was demonstrated utilizing a novel aromatization reaction. We refer to these fascinating structures as "carbon nanohoops" due to their structural similarity to carbon nanotubes. Additionally, we have utilized computational methods to understand the unique properties of these fully conjugated macrocycles. ...[more]

PMID: 19055403

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