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Oxidative carbon-carbon bond formation via allyldimethylsilyl enol ethers.


ABSTRACT: A method for the oxidative alkylation of ketones through intramolecular allyl-group transfer within preformed allyldimethylsilyl enol ethers is reported. A number of examples are detailed, including a study into the effects of resident sterocenters within cyclic enol ethers.

SUBMITTER: Konkol LC 

PROVIDER: S-EPMC2788111 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature