Electron paramagnetic resonance study of the surface hydration of Triton X-100 micelles in water with added monovalent alkali salts.

ABSTRACT: The hydrophobic spin probe 2,2,6,6-tetramethyl-piperidin-1-oxyl-4-yl octadecanoate (TEMPO-stearate) was used to study the hydration of the polar shell of Triton X-100 micelles as functions of the concentration of the electrolytes KCl, NaCl, and LiCl and temperature. It was shown that the hydration of the polar shell of the Triton X-100 micelle decreases with both increasing electrolyte concentration and increasing temperature. The effect of Li(+) on the hydration of the polar shell was found to be smaller than those of Na(+) and K(+), which have almost identical behavior. The effective water concentration decreases from 18.3 to 15.8 M for LiCl and from 18.3 to 13.9 M for NaCl and KCl when the concentration of the electrolyte in the solution increases from 0 to 2.5 M. The dehydration of the

SUBMITTER: Jose BJ 

PROVIDER: S-EPMC2790041 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature