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Total synthesis of lycogarubin C and lycogalic acid.

ABSTRACT: Two complementary concise total syntheses of lycogarubin C (1) and lycogalic acid (2, aka chromopyrrolic acid) are detailed utilizing a 1,2,4,5-tetrazine --> 1,2-diazine --> pyrrole Diels-Alder strategy and enlisting acetylenic dienophiles.

SUBMITTER: Oakdale JS 

PROVIDER: S-EPMC2832087 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

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Total synthesis of lycogarubin C and lycogalic acid.

Oakdale James S JS   Boger Dale L DL  

Organic letters 20100301 5

Two complementary concise total syntheses of lycogarubin C (1) and lycogalic acid (2, aka chromopyrrolic acid) are detailed utilizing a 1,2,4,5-tetrazine --> 1,2-diazine --> pyrrole Diels-Alder strategy and enlisting acetylenic dienophiles. ...[more]

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