Scanning electrochemical microscopy of individual single-walled carbon nanotubes.

ABSTRACT: Here we report on the novel application of scanning electrochemical microscopy (SECM) to enable spatially resolved electrochemical characterization of individual single-walled carbon nanotubes (SWNTs). The feedback imaging mode of SECM was employed to detect a pristine SWNT (approximately 1.6 nm in diameter and approximately 2 mm in length) grown horizontally on a SiO(2) surface by chemical vapor deposition. The resulting image demonstrates that the individual nanotube under an unbiased condition is highly active for the redox reaction of ferrocenylmethyltrimethylammonium used as a mediator. Micrometer-scale resolution of the image is determined by the diameter of a disk-shaped SECM probe rather than by the nanotube diameter as assessed using 1.5 and 10 microm diameter probes. Interestingl

SUBMITTER: Kim J 

PROVIDER: S-EPMC2836802 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature